Who is fritz haber? | who invented fertilizer from nitrogen? | Inventor of chemical warfare |

Fritz Haber made food from the air. He invented a process that takes nitrogen from the air and turns it into fertilizer. This revolutionized agriculture and fed billions of people who otherwise might have starved. He became a hero in his native Germany and won a Nobel Prize. Yet the man who fed billions also had a hand in unspeakable atrocities. Fritz Haber developed poison gas which was then used on both sides in World War One. His work led to the development of the devastating use of gas during the Holocaust....................................

 

Inventor of fertilizer from air



Haber himself was born to a Jewish family in 1868 in Breslau, a city that was then part of Germany but is now located in Poland and is known as Wroclaw. He grew up without his mother, who died weeks after giving birth. Fritz’s father, Siegfried was devastated. He threw himself into his business and became a prosperous dye merchant. Siegfried eventually remarried and had three daughters. He doted on his girls but not on Fritz…who was a reminder of the pain of losing his first wife. After Fritz graduated from an elite school and celebrated with friends in a pub until the wee hours of the morning, his dad was not happy when he overslept and skipped family breakfast. Fritz’s father took his three girls to Fritz’s bedroom and said: “Look well! This is how the life of a drunkard begins!”. That deeply hurt his son. Fritz wanted out of his father’s house. And out of Breslau. He wanted to “break free of the chains that wear me down…” as he wrote to a friend. He decided to go to university to study chemistry; he had already been conducting homemade experiments at his aunt’s house. He studied at several German universities and earned a doctorate in organic chemistry in 1891. Haber also served a year in the military and hoped to be commissioned as an officer in the reserves, but he likely understood that he was rejected because of his Jewish heritage. He later converted to Christianity, possibly to advance his career or to assimilate into German society, where anti-Semitism was rising. Rejection became part of his life. When he applied to join the lab of the esteemed physical chemist Wilhelm Ostwald in Leipzig, his application was denied, while that of his friend and fellow student, Richard Abegg, was accepted. No one appeared to recognize his brilliance. He moved from job to job, working at factories in Eastern Europe through his dad’s connections. Finally, in 1894, at the age of 26, he was hired as an assistant at the Technical University of Karlsruhe, now the Karlsruhe Institute of Technology, in the department of Chemical and Fuel Technology. The university wasn't renowned at the time, but this worked in his favor, as his supervisors gave him the freedom to pursue his own ideas. When someone asked how he managed to master a range of specialties in chemistry so quickly, Haber replied that he “studied every night until 2 am until I got it.” Sometimes, he’d escape into sanatoriums to calm his nerves.

 

He worked so hard that his wife, chemist Clara Immerwahr wrote: “Fritz is so scattered, if I didn’t bring him to his son every once in a while, he wouldn’t even know that he was a father.” (page 63) Clara was also the child of a prosperous merchant. She was also born to a Jewish family and later converted to Christianity. Because she couldn’t obtain good schooling at a young age due to her gender, she made up for it with private tutors. At first, she was only allowed to attend university as a guest, as women were not legally admissible at the time. When that policy changed, she became the first woman in Germany to earn a Ph.D. in chemistry. Yet her career was overshadowed by her husband’s; she couldn’t advance in academia as she was expected to fulfill the role of the professor’s wife.

 

Fritz Haber was working at the university when a British scientist issued a dire warning in 1898. Sir William Crookes warned that “England and all civilized nations stand in deadly peril of not having enough to eat.” He focused his concern on the “bread-eaters of the whole world”, the “great Caucasian race”. He predicted that the world would face famine within decades unless a new source of nitrogen for agricultural fertilizers could be found. Nitrogen is a vital nutrient for plant growth. Scientists relied on limited natural sources of nitrogen to fertilize soil, such as animal manure, bird and bat droppings, or sodium nitrate from Chilean mines - but these resources are limited. Nitrogen is abundant in the atmosphere; 78% of the air is made up of nitrogen. However, in the way that humans can’t drink saltwater, plants can’t use nitrogen directly from the air as a source of nutrition, because of its strong triple bond that makes it difficult for plants to digest. It must be converted into a more useful form. Haber discovered that hydrogen breaks the strong triple bond of nitrogen and converts it to ammonia, or NH3, which is easier for plants to absorb and use. Ammonia is the raw material for common nitrogen-based fertilizers, providing plants with essential nutrients for growth, increasing crop yields and food production. Haber actually struggled at first to find the point at which hydrogen and nitrogen atoms combined into ammonia. He almost gave up until a rival scientist insulted him. Walter Nernst said: “It is unfortunate that so little ammonia is formed in this state of equilibrium, compared with what Haber’s highly inaccurate numbers led us to assume.” That really ticked Haber off; he became obsessed with obtaining ammonia before Nernst did. Haber tried using extreme heat to encourage the formation of ammonia, but that didn’t work. Even 1000 degrees Celsius only produced a minuscule amount of ammonia: one-hundredth of one percent.

 

Haber found an ally in Germany’s largest chemical company BASF which gave him a generous salary to pay for lab equipment and hire assistants. In March 1909, he achieved a breakthrough Haber used a catalyst, osmium, to accelerate the chemical reaction between nitrogen and hydrogen. They combined to produce ammonia with a yield of around 6%. Haber had discovered a process akin to turning lead into gold. It would make him fabulously rich; BASF agreed to pay him 1.5 pfennig - the German cent - in royalties for each kilo of ammonia produced - which added up to a significant sum as the large-scale production of ammonia followed. A chemist and engineer at BASF, Carl Bosch, was responsible for scaling up and commercializing the production of ammonia. The process of synthesizing ammonia is known worldwide as the Haber-Bosch process. Today, an estimated 150 million metric tons of nitrogen is extracted from the air annually, transformed into ammonia, and distributed as nourishing fertilizer for crops. There are long-term environmental concerns to consider. Chemicals from these fertilizers can find their way into water systems, harming water quality and the surrounding ecosystems. But without the Haber-Bosch process, it’s likely that billions of people would not have been able to obtain the food and nutrition they need to survive. About half of our planet’s seven billion people are fed with crops grown using synthetic fertilizers. In 1911, two years after his groundbreaking discovery, Haber became the founding director of a prestigious new research institution, the Kaiser Wilhelm Institute for Physical Chemistry and Electrochemistry. Haber was now a member of the nation’s elite. And Germany was a nation that had great ambition. Haber was determined to support his country in World War I, unlike Albert Einstein, who was horrified that his fellow scientists used their skills to help Germany's war effort. Einstein the pacifist put it this way: “Our entire much-praised technological progress, and civilization generally, could be compared to an axe in the hand of a pathological criminal.”

 

Haber's process for synthesizing ammonia also enabled the creation of explosives. Synthesized ammonia can be converted into nitric acid, which can be used to create nitrates, essential components in powerful explosives. Because of Haber’s process, Germany could fight on, despite British warships blocking nitrate supplies from South America. But explosives would not be Haber’s greatest contribution to his country’s war effort. Haber suggested to German military leaders that they use chlorine gas as a weapon. German High Command was willing to try anything to break the stalemate on the Western front. On April 22, 1915, German troops stationed in Ypres, Belgium, released 5,000 tanks containing chlorine gas which drifted across the battlefield to Allied positions. A British officer described the horror of seeing French colonial soldiers “...with gray faces and protruding eyeballs, clutching their throats and choking as they ran, many of them dropping in their tracks and lying on the sodden earth with limbs convulsed and features distorted in death.” Soldiers panicked and abandoned their positions, creating a four-mile gap in the frontline that the Germans failed to exploit. Several German commanders had actually opposed using poison gas on the battlefield. They thought it was a dishonorable and inhumane way to fight as traditionally, soldiers faced each other directly in combat. Yet, Haber didn’t consider poison gas any worse than bullets. He argued, “...innumerable human lives would be saved if the war could be ended more quickly in this way.” Unfortunately, it did not speed up the war. As gas was heavily dependent on the way the wind blew, and the Allies later used the same weapon themselves.

 

Haber was promoted to the rank of captain in recognition of his efforts in developing chemical warfare. It clearly went to his head. The first president of Israel quoted him as saying: “I was one of the mightiest men in Germany. I was more than a great army commander, more than a captain of industry. I was the founder of industries…All doors were open to me”. On April 1, 1915, Haber returned to Berlin to celebrate his promotion that same night, his wife shot herself with his army pistol in their garden. Their 12-year-old son Hermann found his dying mother. There’s been much speculation about why Clara ended her own life. Decades later, Cousin Paul Krassa, wrote: “She was in despair over the horrible consequences of gas warfare, for which she’d seen the preparations, along with the tests on animals.” Clara had been miserable for a long time. She struggled with the gender roles expected of her, leaving her own ambitions to fall by the wayside. She detailed her suffering in a letter to her mentor Richard Abegg, who had introduced her to her husband. “What Fritz has gained during these last eight years, I have lost, and what's left of me, fills me with the deepest dissatisfaction.” Haber never publicly defended himself against speculation that it was his work that caused his wife’s death.

 

We got a glimpse of his emotional state when he wrote to his former mentor, chemist Carl Engler, six weeks later: “For a month I doubted that I could keep going. But now the war, with its dreadful images and constant demands on all my powers, has made me calmer…” A day after Clara took her own life, Haber returned to the front lines. He then supervised the development of an even more horrific weapon – mustard gas. Unlike chlorine gas, mustard gas didn’t blow away with the wind and instead, stuck to clothes, causing painful blisters and blinding soldiers who got it in their eyes. Haber called it a “fabulous success.” By the end of the war, an estimated 90,000 soldiers had been killed by poison gas, and more than a million suffered injuries. Despite Haber’s efforts, Germany lost the war. The effectiveness of gas diminished as the Allies started using the same weapon. It didn’t help that Germany made a major strategic blunder when it began to attack both military and civilian ships without distinguishing between the two, which brought the U.S. into the war and tilted the balance of power. After Germany surrendered, Haber worried that he’d be tried as a war criminal. He moved with his son, his second wife Charlotte, and their young daughter to neutral Switzerland for a time and even grew a beard as a disguise. However, instead of being prosecuted for war crimes, Haber was honored with the Nobel Prize in Chemistry in 1919. The Nobel Prize committee declared his synthesis of ammonia "the greatest benefit to mankind”. But the award was controversial because of Haber’s development of chemical weapons. Two French scientists who had been offered prizes turned them down in protest.

 

Although he won the Nobel Prize, his legacy is forever tarnished. Haber failed to realize that his nation would use his chemical weapon against innocent civilians. The irony is that his own people, the Jewish people, would become the primary victims. The Nazis used Zyklon B to exterminate over a million people in concentration camps in World War Two. Scientists at Haber’s Institute had developed an earlier version of Zyklon to get rid of insect infestations in flour mills and granaries. Then they introduced another version of the pesticide that was easier to handle and more powerful without imagining it would ever be used on people. Haber’s own extended family perished in Hitler’s gas chambers. Anti-Semitism grew after the First World War as some Germans felt the Jewish people were responsible for the country’s significant problems. Hitler’s Nazi party capitalized on the widespread unemployment, poverty, and unrest to fuel its rise to power. Despite his contributions to his beloved Germany, Haber realized he would soon become a target of Nazi repression. His conversion to Christianity was irrelevant; it was his ancestry that mattered. He was forced to fire some Jewish scientists at his government-funded research institute and, a few days later, Haber resigned his own position in protest. In his resignation letter to the Prussian minister of culture, Haber emphasized his lifelong principle: "My tradition requires that when choosing coworkers for a scientific post, I consider only the professional and personal characteristics of the applicant, without regard for their racial makeup." “My tradition requires that when choosing coworkers for a scientific post, I consider only the professional and personal characteristics of the applicant, without regard for their racial makeup. You cannot expect a man in his sixty-fifth year to change the thinking that has guided him for the past thirty-nine years of university life, and you will understand that the pride with which he served his German homeland all his life now dictates this request for retirement.” Planck appealed directly to Hitler, trying to convince him that forcing valuable Jews to leave would hurt Germany. Hitler apparently flew into a rage. Nazi policy left no room for exceptions, not even for the man who had arguably contributed more to Germany’s might during World War I than anyone else.

 

Einstein, who had been traveling when the Nazis came to power and declared he wouldn’t return to Germany, put it this way in a letter to Haber: “I can imagine your inner conflicts. It is somewhat like having to abandon a theory on which you have worked your whole life. It’s not the same for me as I never believed in it in the least.” Einstein put it more delicately in a letter to Haber’s son after Haber’s death. “It was the tragedy of the German Jew: the tragedy of unrequited love.” Haber tried his entire life to be the perfect German. Despite his religious conversion, despite one of the greatest scientific discoveries of all time, despite his attempt to save his country, the only thing that mattered, in the end, was that he was Jewish. He summed up his feelings in a letter to the prominent German chemist Richard Willstätter: “I am bitter as never before, and the feeling that this is unbearable increases by the day.”

 

As if it could not be any worse, Haber found himself in a dire financial situation. Hyperinflation after World War One had diminished the value of his royalties from his ammonia patents. He also had to financially support his second wife after their divorce. The global financial crisis of 1929 ate away what was left of his finances. He desperately searched for a way out of his precarious situation. A former foe actually came to his rescue. British chemist William Pope worked on the development of gas warfare for the British and offered Haber a temporary position at the University of Cambridge. By then, Haber’s health had worsened. He eventually left England to seek treatment at a sanatorium in Switzerland. He got as far as Basel when his heart failed. On the night of January 29, 1934, Fritz Haber died. He was 65 years old. Haber had requested to his son Hermann that this to be written on his gravestone: “In war and peace, as long as it was granted him, a servant of his homeland.” Hermann refused his father’s wishes. He also refused to attend his father’s memorial service believed he couldn’t be honored in the country that had rejected him. Scientist Max Planck courageously organized a service in Berlin on the one-year anniversary of Haber’s death despite intimidation by the Nazis, who ordered state employees to stay away. Many of the scientists' wives bravely attended. The great industrialist Carl Bosch was also there. He owed his career to Haber.

 

The Haber-Bosch process led to the stunning growth of Bosch's company, BASF, which later merged with other chemical companies to form the conglomerate I.G. Farben which the Americans seized after WWII. Although Haber tried to distance himself from his Jewish heritage nearly his whole life, in his final days, he seemed to have a change of heart. He struck up a friendship with the Zionist Chaim Weizmann, who fought to establish the state of Israel. Haber lamented to Weizmann: “I was one of the mightiest men in Germany…At the end of my life I find myself a bankrupt. When I am gone and forgotten your work will stand, a shining monument, in the long history of our people.” Despite his significant contribution to the field of chemistry, there is no statue of Fritz Haber in Germany or anywhere. The only place that bears his name is the institute he once led. The Kaiser Wilhelm Institute was renamed The Fritz Haber Institute of the Max Planck Society in 1953. One of the institute’s directors said that the name is a reminder that science can be used as a tool for good and also as a tool for evil. Despite the controversy surrounding Fritz Haber, his contributions to science have left a lasting impact on the world.

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